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Welcome to GCSE Edexcel Science revision.

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Unit S P 6: Radioactivity.

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Thomson’s plum-pudding model described negative electrons embedded in spread-out positive charge.

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Later evidence changed this model.

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Rutherford’s team directed positive alpha particles at thin gold foil.

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Most passed through; some were deflected; very few were deflected through large angles or back towards the source.

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Most passing through showed the atom is mostly empty space.

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Large deflections showed positive charge and much of the mass concentrated in a tiny nucleus; the plum-pudding model could not explain them.

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A small concentrated nucleus explains rare large deflections.

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The nuclear model has positive protons and neutral neutrons in the nucleus, with negative electrons outside it.

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Rutherford’s original model did not yet include the later discovery of neutrons.

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Protons have relative charge plus 1 and mass about 1; neutrons charge 0 and mass about 1; electrons charge minus 1 and much smaller mass, about 1 divided by 1840 of a proton.

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Atomic number Z counts protons; mass or nucleon number A counts protons plus neutrons.

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Neutrons equals A minus Z.

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In a neutral atom, electrons equals protons; ions have unequal numbers.

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A neutral sodium-23 atom also has 11 electrons.

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Isotopes have the same proton number but different neutron numbers.

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Carbon-12, carbon-13 and carbon-14 are isotopes of carbon.

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Bohr’s model uses fixed electron energy levels or shells.

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Electrons absorb energy to move to higher levels and emit electromagnetic radiation when returning to lower levels.

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When electrons move between energy levels, different energy changes produce radiation of different frequencies.

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The separate lines in emission and absorption spectra show that the energy levels have fixed, distinct values.

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Different elements produce different line patterns.

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Ionisation is removal or addition of electrons to form ions.

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Radiation that removes an electron leaves a positive ion; it does not change the number of protons.

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Background radiation is radiation present around us even without a nearby experimental source.

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Natural sources include rocks, radon gas, cosmic radiation and naturally radioactive materials in food.

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Artificial sources include medical uses and smaller contributions from nuclear industry and past activities.

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Contributions vary with location and occupation.

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A Geiger, Müller tube and counter detect ionising radiation as pulses.

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Count rate is counts per second or minute; not every decay in the source is detected.

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Source activity is the number of nuclear decays per second, measured in becquerels (becquerels).

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One becquerels means one decay per second; activity and detector count rate are different quantities.

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Measure background without the source for a suitable time.

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Divide counts by time, then subtract this background count rate from the source-plus-background rate measured consistently.

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Radioactive counts fluctuate randomly.

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Count for longer and repeat to reduce relative random uncertainty; keep distance, detector position and counting time controlled.

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Photographic film darkens on exposure.

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Film badges and other dosimeters monitor exposure; they do not shield the wearer or replace limiting exposure time.

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An unstable nucleus can decay spontaneously, emitting radiation.

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Decay is random: it is impossible to predict when one particular nucleus will decay.

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An alpha particle is a helium nucleus: two protons and two neutrons, charge plus 2.

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Alpha is strongly ionising, short-range in air and stopped by paper or the outer skin layer.

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Beta minus is a fast electron emitted from the nucleus when a neutron changes into a proton.

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It is not an electron ejected from an outer shell.

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Beta plus is a positron, the positive counterpart of an electron, emitted when a proton changes into a neutron.

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Both beta types are moderately penetrating and ionising compared with alpha and gamma.

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A thin aluminium sheet can substantially stop beta radiation; required thickness depends on beta energy.

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Beta travels further in air than alpha.

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Gamma is high-frequency electromagnetic radiation emitted when a nucleus loses excess energy.

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It has no charge or rest mass and does not alter A or Z.

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Gamma is highly penetrating and weakly ionising compared with alpha.

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Thick lead or concrete reduces intensity substantially, rather than guaranteeing every gamma photon is stopped.

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These are qualitative comparisons; shielding reduces the radiation reaching a detector.

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A neutron can also be emitted from a nucleus: mass number falls by 1 and proton number stays unchanged.

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Different radiation types need suitable shielding.

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In alpha decay, A decreases by 4 and Z decreases by 2.

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For example, radium-226 (Z equals 88) becomes radon-222 (Z equals 86) plus helium-4 (Z equals 2).

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In beta-minus decay, A stays unchanged and Z increases by 1.

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The emitted electron has nucleon number 0 and charge number minus 1, keeping equation totals balanced.

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In beta-plus decay, A stays unchanged and Z decreases by 1.

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The emitted positron has nucleon number 0 and charge number plus 1.

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In gamma emission, A and Z stay the same.

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The nucleus has less energy, but it still has the same numbers of protons and neutrons: it is the same nuclide.

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Check nuclear equations by balancing total nucleon numbers and total charge numbers on both sides.

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The identity of the element is set by Z, not by A alone.

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Balance nucleon numbers and charge numbers in each equation.

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Half-life is the time for half the undecayed nuclei in a large sample to decay, or for the activity to halve.

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It does not mean half the total material vanishes.

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The activity decreases as fewer undecayed nuclei remain.

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After 1, 2 and 3 half-lives, the fraction remaining is one half, one quarter and one eighth.

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After n half-lives, remaining activity equals initial activity divided by two to the power n.

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Time elapsed equals number of half-lives times half-life duration.

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If activity starts at 80 becquerels and half-life is 5 years, activities after 5, 10 and 15 years are 40, 20 and 10 becquerels.

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Equal time intervals halve the activity; the curve is exponential, not linear.

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To read half-life from a graph, choose an activity, find when it falls to half, and subtract the times.

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Check several pairs and subtract background from measured count-rate data first.

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Half-life lets us predict how a large radioactive sample will behave overall, even though individual decays are random.

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Smaller samples show more variation.

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As fewer undecayed nuclei remain, fewer decay each second: the decrease is not a straight line.

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Ionising radiation can damage cells and D N A, causing mutations and increasing cancer risk.

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Effects depend on dose and exposure; not every exposure causes a tumour.

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Keep sources at a distance using tongs, minimise exposure time, use appropriate shielding and store them securely.

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Follow supervised handling procedures and never point a source towards someone.

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Irradiation means exposure to radiation.

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Contamination means radioactive material gets onto or into an object or person, so exposure can continue while it remains there.

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Contamination can continue irradiating the person until the material is removed or decays.

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Ordinary irradiation does not mean radioactive material has been deposited.

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Contamination may need removal and containment; merely moving away from the original source is insufficient.

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Alpha is particularly dangerous if an alpha-emitting material enters the body: strong ionisation affects nearby tissue without the skin barrier.

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Penetrating gamma is also an external-exposure hazard.

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Medical staff monitor dose and limit time near sources, use shielding and distance, and balance treatment or diagnostic benefit against radiation risk.

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An ionisation smoke alarm can use an alpha source to ionise air and allow a small current.

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Smoke disrupts this current, triggering an alarm; the source is safely enclosed and should not be handled by users.

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Gamma irradiation can sterilise medical equipment or reduce microorganisms in food.

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Irradiation exposes the item to radiation and does not automatically make it radioactive; contamination means radioactive material is actually transferred.

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A beta source and detector can monitor thin sheet thickness: a thicker sheet absorbs more radiation, reducing detector count.

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Choose radiation with suitable penetration and a source whose output changes slowly enough for the application.

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A radioactive tracer can be introduced into the body and detected externally.

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It needs suitable radiation penetration and a half-life long enough for observation but short enough to limit prolonged exposure.

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PET scanning uses positron-emitting tracers.

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A positron meeting an electron leads to gamma photons that are detected to map activity; short-lived tracers must be produced nearby so useful activity remains when administered.

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External radiotherapy directs radiation at a tumour from outside the body.

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Internal treatment places or delivers a source close to the tumour; targeting and dose planning aim to damage cancer while limiting harm to healthy tissue.

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The risk from a source depends on its activity, radiation type, penetration, exposure route and half-life.

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A very short half-life can mean high initial activity for a fixed initial number of nuclei; a long half-life can create a prolonged contamination or waste problem.

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Nuclear fission splits a heavy nucleus into smaller daughter nuclei.

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A uranium-235 nucleus can absorb a neutron, become unstable and split, releasing energy and two or more neutrons; several different daughter pairs are possible.

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Released neutrons can cause further fissions, forming a chain reaction.

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A controlled reactor maintains a suitable average number of further fissions rather than allowing an uncontrolled rapidly growing reaction.

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Control rods absorb neutrons; they do not act as the moderator.

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A moderator slows neutrons so they are more likely to produce further fission in suitable fuel.

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Control rods absorb neutrons; inserting them further reduces the reaction rate, while withdrawing them can increase it.

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Energy from fission heats a coolant.

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Heat is used to produce steam, which turns a turbine connected to a generator; the nuclear reaction does not itself directly send electricity down the power line.

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Fission products are radioactive and require shielding, cooling and suitable waste management.

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Some wastes stay hazardous for long periods; short half-life does not mean immediate absence of risk.

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Nuclear generation has low direct carbon-dioxide emissions and can provide steady power,

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but evaluate fuel extraction,

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construction,

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cost,

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accident risk,

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public perception,

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safety systems and waste disposal.

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Low direct emissions do not mean zero whole-life emissions.

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Nuclear fusion joins smaller nuclei to make a larger nucleus, releasing energy.

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The products have slightly less total mass than the starting particles; the mass difference corresponds to released energy.

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This is a comparison of processes, not a sequence in which fission becomes fusion.

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Fusion powers stars.

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Positively charged nuclei repel each other,

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so high temperature is needed for sufficient particle energy and suitable pressure or confinement is needed to sustain useful reaction rates.

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Fission splits heavy nuclei; fusion joins light nuclei.

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Radioactive decay, fission and fusion can all release nuclear energy, but they are different processes.

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Generating power by controlled fusion is difficult.

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The very hot ionised gas (plasma) must be kept contained and stable, and the equipment must survive extreme conditions.

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The complete system must produce more useful energy than it uses.

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Producing fusion in a laboratory is not enough by itself to make an economical power station.

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Compare proposed fusion and fission systems using evidence about fuel, waste, safety, technical readiness, costs and useful output.

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Do not describe fusion as an already universal replacement for current electricity generation.

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That completes Radioactivity.

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Revisit the notes and test yourself on the revision website.
